化工社化工社 化学情報印刷レポート · 研究参考用
Trimethylamine → 1,3-Dihydroxy-5-trimethylsiloxyadamantane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Trimethylamine | HCID 1146 | — |
| 反応物 | Chlorotrimethylsilane | HCID 6397 | — |
| 反応物 | 1,3,5-Adamantanetriol | HCID 9899022 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 1,3-Dihydroxy-5-trimethylsiloxyadamantane | HCID 21930710 | — |
反応手順
This 1,3,5-trihydroxyadamantane was dissolved in methylene chloride. To this solution were added a small amount of trimethylamine, and then an equimolar amount of trimethylsilyl chloride. Reaction was carried out at room temperature. The reaction product was partitioned by high performance liquid chromatography to obtain 1,3-dihydroxy-5-trimethylsiloxyadamantane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06660450B2 |
| 出典データセット | uspto-grants-2003_12 |
| ORD ID | ord-609fd757932c4d9781e7d8b82ed4d6a3 |
| 出典メモ | uspto-grants-2003_12 |