Sodium Azide → p-Azidomethylphenyltrimethoxysilane
反応式
Cl[CH2:2][C:3]1[CH:8]=[CH:7][C:6]([Si:9]([O:14][CH3:15])([O:12][CH3:13])[O:10][CH3:11])=[CH:5][CH:4]=1.[N-:16]=[N+:17]=[N-:18].[Na+]>>[N:16]([CH2:2][C:3]1[CH:8]=[CH:7][C:6]([Si:9]([O:14][CH3:15])([O:12][CH3:13])[O:10][CH3:11])=[CH:5][CH:4]=1)=[N+:17]=[N-:18]参加物
3
反応条件
- 温度
- 150 °C
実験手順
1.0 mole of p-chloromethylphenyltrimethoxysilane and 1.1 moles of sodium azide were heated in the presence of 5 mole percent of the catalyst described in Example 1 (a) for three hours under stirring at 150° C. Then the salt formed was separated and the subsequent distillation under reduced pressure gave the p-azidomethylphenyltrimethoxysilane in a yield of 89 weight percent with the following characteristics:
後処理
- customThen the salt formed
- customwas separated
- distillationthe subsequent distillation under reduced pressure
出典と根拠
- ORDレコード
- ord-7fe7420835bc4e11b7ca2ca2173caf0c
- 出典データセット
- uspto-grants-1983_08
- 特許番号
- US04401598
反応ノート
読み込み中…