Thionyl Chloride → HCID 12232349、化合物
反応式
[F:1][C:2]1[CH:3]=[C:4]([C:7]([S:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:8][CH:9]=1)[CH2:5]O.S(Cl)([Cl:19])=O>C1C=CC=CC=1>[F:1][C:2]1[CH:3]=[C:4]([C:7]([S:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:8][CH:9]=1)[CH2:5][Cl:19]参加物
4
実験手順
129 g of 3-fluoro-6-(phenylthio)-benzyl alcohol are dissolved in 385 ml of benzene and heated under reflux. 73 ml of thionyl chloride are added thereto and the resulting mixture is boiled for a further 30 minutes. The mixture is evaporated under reduced pressure. There is obtained 3-fluoro-6-(phenylthio)-benzyl chloride as a red-brown oil.
後処理
- temperatureheated
- temperatureunder reflux
- customThe mixture is evaporated under reduced pressure
出典と根拠
- ORDレコード
- ord-db80e4db199b480a97512429479f9c64
- 出典データセット
- uspto-grants-1977_02
- 特許番号
- US04006145
反応ノート
読み込み中…