Benzoyl fluoride, 4-(trifluoromethoxy)- → HCID 21452998、化合物

HRID 436659

反応式

HRID 436659 の反応式
[F:1][C:2]([F:14])([F:13])[O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8](F)=[O:9])=[CH:6][CH:5]=1.[CH2:15]([NH2:24])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH:21]([NH2:23])[CH3:22]>C(Cl)CCl>[CH3:22][CH:21]([NH:23][C:8](=[O:9])[C:7]1[CH:11]=[CH:12][C:4]([O:3][C:2]([F:1])([F:13])[F:14])=[CH:5][CH:6]=1)[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][NH:24][C:8](=[O:9])[C:7]1[CH:11]=[CH:12][C:4]([O:3][C:2]([F:14])([F:13])[F:1])=[CH:5][CH:6]=1

参加物

4

反応物 2

HCID 67612Benzoyl fluoride, 4-(trifluoromethoxy)-HCID 19967785Octane-1,7-diamine

生成物 1

HCID 21452998HCID 21452998、化合物

試薬・触媒・溶媒 1

HCID 111,2-Dichloroethane溶媒2 回

実験手順

m.p. 137°-138° C., 15.1 g., was prepared as in Example 20 using 18.7 g. of 4-trifluoromethoxybenzoyl fluoride in 50 ml. of ehtylene dichloride, 6.0 g. of 1,7-octanediamine in 100 ml. of ethylene dichloride, 13.8 g. of anhydrous potassium carbonate, and recrystallization from chloroform.

後処理

  1. custom, was prepared as in Example 20 using 18.7 g
  2. customof anhydrous potassium carbonate, and recrystallization from chloroform

出典と根拠

ORDレコード
ord-86f39d7689d2494182f97a30f64e1f83
出典データセット
uspto-grants-1977_02
特許番号
US04009208

関連ノート

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