Methane → 2-(6-Carboxyhexyl)benzyl alcohol

HRID 437987

反応式

HRID 437987 の反応式
[C:1]([OH:9])(=[O:8])[CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH4:10]>C(O)C>[C:1]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:10]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH2:1][OH:8])([OH:9])=[O:8]

参加物

4

反応物 2

HCID 297MethaneHCID 29373Heptenoic acid

生成物 1

HCID 539714442-(6-Carboxyhexyl)benzyl alcohol

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A solution of 2.30 g. of the above heptenoic acid in 100 ml. of ethanol is stirred with 5 g. of activated charcoal for 30 minutes and filtered. The filtrate is hydrogenated at atmospheric pressure in the presence of 143 mg. of platinum oxide. The solution is filtered, evaporated and recrystallized from toluene to yield 2-(6-carboxyhexyl)benzyl alcohol as white crystals having a melting point of 75°-77° C.

後処理

  1. filtrationfiltered
  2. filtrationThe solution is filtered
  3. customevaporated
  4. customrecrystallized from toluene

出典と根拠

ORDレコード
ord-a434d3d6d1b8480e8bb79ac2a2025f06
出典データセット
uspto-grants-1977_06
特許番号
US04032656

関連ノート

読み込み中…