5-[(4-Chlorophenyl)methylidene]-2,2-dimethylcyclopentan-1-one → 5-(4-Chlorobenzyl)-2,2-dimethylcyclopentanone

HRID 440571

反応式

HRID 440571 の反応式
[Cl:1][C:2]1[CH:16]=[CH:15][C:5]([CH:6]=[C:7]2[CH2:11][CH2:10][C:9]([CH3:13])([CH3:12])[C:8]2=[O:14])=[CH:4][CH:3]=1.[H][H]>C(O)C.[C].[Pd]>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:6][CH:7]2[CH2:11][CH2:10][C:9]([CH3:13])([CH3:12])[C:8]2=[O:14])=[CH:15][CH:16]=1

参加物

5

反応物 2

HCID 534210215-[(4-Chlorophenyl)methylidene]-2,2-dimethylcyclopentan-1-oneHCID 178418361HCID 178418361、化合物

生成物 1

HCID 114248965-(4-Chlorobenzyl)-2,2-dimethylcyclopentanone

試薬・触媒・溶媒 2

HCID 178418390HCID 178418390、化合物触媒HCID 702Ethanol溶媒

実験手順

5 g of 2-(4-chlorobenzylidene)-5,5-dimethylcylopentanone (prepared in Example 5) was dissolved in 40 ml of ethanol, and 60 mg palladium-carbon (10%) was added to the mixture. The hydrogenation reaction was carried out under normal pressure until theoretical amount of hydrogen was absorbed.

後処理

  1. customThe hydrogenation reaction
  2. customwas absorbed

出典と根拠

ORDレコード
ord-374bf906581b40649dcba35c765543d2
出典データセット
uspto-grants-1996_05
特許番号
US05519160

関連ノート

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