Trifluoroacetic acid → 3(2H)-Benzofuranone, 2-(methylthio)-
反応式
[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8](=[O:13])[CH2:9][S:10]([CH3:12])=O.FC(F)(F)C(O)=O>C1C=CC=CC=1>[CH3:12][S:10][CH:9]1[C:8](=[O:13])[C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[O:1]1参加物
4
実験手順
2-Hydroxy-1-[(methylsulfinyl)acetyl] benzene (1.5 g 0.0075m) and trifluoroacetic acid (1.5 g) are refluxed in benzene (25 ml) for one hour under nitrogen. The solvent is removed under reduced pressure to give a pale yellow oil which crystallizes on standing. Recrystallization from ethanol gave white crystals, (0.611 g 45%), m.p. 81°-82° C.
後処理
- customThe solvent is removed under reduced pressure
- customto give a pale yellow oil which
- customcrystallizes
- customRecrystallization from ethanol
- customgave white crystals, (0.611 g 45%), m.p. 81°-82° C.
出典と根拠
- ORDレコード
- ord-cbb65238e3684529884f0d29f08bb525
- 出典データセット
- uspto-grants-1977_08
- 特許番号
- US04045451
反応ノート
読み込み中…