反応式
[C:1](=[O:14])(OC(Cl)C(Cl)(Cl)Cl)[O:2][C:3]([CH3:6])([CH3:5])[CH3:4].[NH:15]1[CH:19]=[CH:18][N:17]=[CH:16]1.C(=O)([O-])[O-].[K+].[K+]>C1COCC1>[C:3]([O:2][C:1]([C:16]1[NH:15][CH:19]=[CH:18][N:17]=1)=[O:14])([CH3:4])([CH3:5])[CH3:6]参加物
5
反応条件
- 温度
- 20 °C
実験手順
5 g (17.5 mmol) of tert-butyl 1,2,2,2-tetrachloroethyl carbonate dissolved in 10 ml of THF are added at 0° C. to a solution of imidazole (1.2 g; 17.6 mmol) in THF (20 ml) in the presence of 5M aqueous potassium carbonate solution (5 ml). The mixture is stirred for 1 hour at 20° C., and the organic phase is decanted and washed with 10 ml of saturated aqueous NaCl solution.
後処理
- customthe organic phase is decanted
- washwashed with 10 ml of saturated aqueous NaCl solution
出典と根拠
- ORDレコード
- ord-18ed9719ba5540d59af2fe55eab3dddb
- 出典データセット
- uspto-grants-1988_02
- 特許番号
- US04725680
関連ノート
読み込み中…