Phenyl phenylglyoxylate → Phenyl benzoate

HRID 443085

反応式

HRID 443085 の反応式
[C:1]1([C:7](=O)[C:8]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3]C=1>[Cl-].C1([P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(Cl)(Cl)Cl>[C:8]([O:10][C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)(=[O:9])[C:7]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:1]=1

参加物

4

反応物 1

HCID 13975017Phenyl phenylglyoxylate

生成物 1

HCID 7169Phenyl benzoate

試薬・触媒・溶媒 2

HCID 164911Tetraphenylphosphonium Chloride触媒HCID 6212Chloroform溶媒

実験手順

The decarbonylation reaction of phenyl phenylglyoxylate (PPG) was repeated in the manner as described in Example 79, except that neither tetraphenylphosphonium chloride nor chloroform was employed. The results are also set forth in Table 12.

出典と根拠

ORDレコード
ord-9fbbfbfddd16461f95e28fccac4f61d6
出典データセット
uspto-grants-1999_04
特許番号
US05892091

関連ノート

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