Lithium Hydroxide → HCID 12912741、化合物
反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7](Cl)=[CH:6][N:5]=1)([O-:3])=[O:2].[Cl:11][C:12]1[CH:17]=[CH:16][C:15]([SH:18])=[CH:14][CH:13]=1.[OH-].[Li+].CN(C=O)C>O>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:18][C:15]2[CH:16]=[CH:17][C:12]([Cl:11])=[CH:13][CH:14]=2)=[CH:6][N:5]=1)([O-:3])=[O:2]参加物
6
実験手順
2-Nitro-5-chloropyridine (9.5 grams), 4-chlorothiophenol (8.7 grams), and lithium hydroxide (4 grams) were mixed in 100 ml. of DMF and the reaction mixture was stirred overnight (about 18 hours) at room temperature. The reaction mixture was then poured into water and the product separated by filtration and crystallized from ethanol-hexanes, yield, 10.0 grams, m.p., 96°-98° C.
後処理
- customthe product separated by filtration
- customcrystallized from ethanol-hexanes
- customyield
- customm.p., 96°-98° C.
出典と根拠
- ORDレコード
- ord-59219e31105d4d478d72800c39063248
- 出典データセット
- uspto-grants-1981_04
- 特許番号
- US04264605
反応ノート
読み込み中…