Propane sultone → 3-(3-Hexadecyl-1-imidazolio)-1-propanesulfonate

HRID 45767

反応式

HRID 45767 の反応式
[CH2:1]([N:17]1[CH:21]=[CH:20][N:19]=[CH:18]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[CH2:22]1[CH2:28][S:25](=[O:27])(=[O:26])[O:24][CH2:23]1>CC(C)=O>[CH2:1]([N:17]1[CH:21]=[CH:20][N+:19]([CH2:23][CH2:22][CH2:28][S:25]([O-:27])(=[O:26])=[O:24])=[CH:18]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

参加物

4

反応物 2

HCID 14264Propane sultoneHCID 124156141-Hexadecyl-1H-imidazole

生成物 1

HCID 873187683-(3-Hexadecyl-1-imidazolio)-1-propanesulfonate

試薬・触媒・溶媒 1

HCID 180Acetone溶媒2 回

実験手順

12.3 g of N-hexadecylimidazole was dissolved in 80 ml of acetone, and the mixture was cooled in an ice-water bath. Into the resultant, a solution in which 5.13 g of 1,3-propanesultone was dissolved in 80 ml of acetone was dripped, and after the dripping was completed, the resultant was stirred at room temperature. After the completion of the reaction, the resultant was filtered to obtain a precipitate. The precipitate was dried under reduced pressure, whereby 15.4 g of 3-(3-hexadecyl-1-imidazolio)-1-propanesulfonate (M-1) represented by the chemical formula (M-1) was obtained.

後処理

  1. temperaturethe mixture was cooled in an ice-water bath
  2. customAfter the completion of the reaction
  3. filtrationthe resultant was filtered
  4. customto obtain a precipitate
  5. dry with materialThe precipitate was dried under reduced pressure, whereby 15.4 g of 3-(3-hexadecyl-1-imidazolio)-1-propanesulfonate (M-1)
  6. customwas obtained

出典と根拠

ORDレコード
ord-b0d4e10ac7aa4208b2090870c6d587c7
出典データセット
uspto-grants-2013_09
特許番号
US08541591B2

関連ノート

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