化工社化工社 化学情報印刷レポート · 研究参考用
1,3-Cyclohexadiene → 5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,3-Cyclohexadiene | HCID 11605 | — |
| 反応物 | trans-1,2-Bis(phenylsulfonyl)ethylene | HCID 5367099 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene | HCID 12778411 | 96.5% |
反応手順
29.33 g of trans-1,2-diphenylsulfonylethylene was dissolved in 200 ml of toluene, and then, 11.4 ml of 1,3-cyclohexadiene was added, followed by dry distillation for 21 hours and then by recrystallization to obtain 35.66 g (yield: 96.5%) of 5,6-diphenylsulfonyl-bicyclo-[2,2,2]oct-2-ene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07193237B2 |
| 出典データセット | uspto-grants-2007_03 |
| ORD ID | ord-a06b7c538b6d48bcb165f87e5c36eb9b |
| 出典メモ | uspto-grants-2007_03 |