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HRID459601

反应详情

EQUATION

反应方程式

HRID 459601 的结构方程式

REACTANTS

反应物

2
结构：C1=CCCC=C1
HCID11605

1,3-Cyclohexadiene

C6H8

结构：O=S(=O)(/C=C/S(=O)(=O)c1ccccc1)c1ccccc1
HCID5367099

1,1′-[(1E)-1,2-Ethenediylbis(sulfonyl)]bis[benzene]

C14H12O4S2

PRODUCTS

生成物

1
结构：O=S(=O)(c1ccccc1)C1C2C=CC(CC2)C1S(=O)(=O)c1ccccc1
HCID12778411

5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene

C20H20O4S2

收率 96.5%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

29.33 g of trans-1,2-diphenylsulfonylethylene was dissolved in 200 ml of toluene, and then, 11.4 ml of 1,3-cyclohexadiene was added, followed by dry distillation for 21 hours and then by recrystallization to obtain 35.66 g (yield: 96.5%) of 5,6-diphenylsulfonyl-bicyclo-[2,2,2]oct-2-ene.

WORKUP

后处理

  1. customby dry
  2. distillationdistillation for 21 hours
  3. customby recrystallization