Thionyl Chloride → HCID 53698365、化合物

反応式

[CH2:1]([C:9]1[CH:19]=[CH:18][C:12]([CH:13]=[CH:14][C:15](O)=[O:16])=[CH:11][CH:10]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].S(Cl)([Cl:22])=O>>[CH2:1]([C:9]1[CH:19]=[CH:18][C:12]([CH:13]=[CH:14][C:15]([Cl:22])=[O:16])=[CH:11][CH:10]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

参加物

反応物 2

HCID 24386Thionyl Chloride

HCID 542659983-(4-Octylphenyl)prop-2-enoic acid

生成物 1

HCID 53698365HCID 53698365、化合物

実験手順

1.8 G. of p-n-octylcinnamic acid, prepared in a manner analogous to that described in Example 1, are boiled in 25 ml. of thionyl chloride for 30 minutes. The excess thionyl chloride is removed by distillation. The residue is taken up twice in absolute toluene, concentrated on a rotary evaporator and dried. There is thus obtained crude p-n-octylcinnamic acid chloride.

後処理

customThe excess thionyl chloride is removed by distillation
concentrationconcentrated on a rotary evaporator
customdried

出典と根拠

ORDレコード: ord-019bb038b60a4c4fbb3b562d0fd56bf3
出典データセット: uspto-grants-1977_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04061587

反応ノート

読み込み中…

参加物