m-Methylallylbenzene → HCID 86735263、化合物
反応式
[CH3:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1.C1C(C(OO)=[O:18])=CC=CC=1>C(Cl)(Cl)Cl>[CH3:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:10]2[O:18][CH:9]2[CH:8]=[CH:7][CH:6]=1参加物
4
実験手順
To 5.3 g of m-methylallylbenzene was added 85 ml of chloroform solution containing perbenzoic acid and the mixture was allowed to stand at room temperature overnight. The resulting solution was washed with sodium hydroxide solution, Mohr's salt solution and then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was distilled under reduced pressure to give 1.1 g (yield 19%) of m-methylallylbenzene oxide having a boiling point of 90° C/7 mmHg.
後処理
- washThe resulting solution was washed with sodium hydroxide solution, Mohr's salt solution
- dry with materialwater, and dried over anhydrous sodium sulfate
- customThe solvent was evaporated
- customto obtain the residue, which
- distillationwas distilled under reduced pressure
出典と根拠
- ORDレコード
- ord-004dbd67dbe14e27a54145f8fbc7017f
- 出典データセット
- uspto-grants-1977_12
- 特許番号
- US04062862
反応ノート
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