Benzoyl Peroxide → HCID 86735267、化合物

HRID 461412ノート

反応式

HRID 461412 の反応式
C1C(C(OO)=[O:8])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[CH2:29]([CH2:32][CH2:33][CH2:34][C:35]1[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=1)[CH:30]=[CH2:31]>C(Cl)(Cl)Cl>[CH2:29]([CH:32]=[CH:33][CH2:34][C:35]1[CH:36]=[CH:37][CH:38]2[O:8][CH:39]2[CH:40]=1)[CH2:30][CH3:31]

参加物

5

反応物 3

HCID 7187Benzoyl PeroxideHCID 519188hex-5-enylbenzeneHCID 523077Perbenzoic acid

生成物 1

HCID 86735267HCID 86735267、化合物収率 76%

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

To perbenzoic acid in chloroform prepared from 65.5 g of benzoylperoxide was added 1.45 g of p-allylpropylbenzene and the mixture was allowed to stand at 5° C for 6 days. After the completion of the reaction, the mixture was washed with 2% sodium hydroxide solution, water, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was distilled under reduced pressure to give 12.1 g (yield 76%) of p-n-propylallylbenzene oxide as colourless liquid.

後処理

  1. customAfter the completion of the reaction
  2. washthe mixture was washed with 2% sodium hydroxide solution, water, Mohr's salt solution
  3. dry with materialwater, and dried over anhydrous sodium sulfate
  4. customThe solvent was evaporated
  5. customto obtain the residue, which
  6. distillationwas distilled under reduced pressure

出典と根拠

ORDレコード
ord-5a7c4a84a60c48728305ae320bc3d928
出典データセット
uspto-grants-1977_12
特許番号
US04062862

反応ノート

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