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Methanol → Trimethylbenzyl ammonium cinnamate

HRID 461601
ノート
印刷プレビュー

反応式

HRID 461601 の反応式
[CH2:1](Cl)/[CH:2]=[CH:3]\[OH:4].C[OH:7].[OH-].[CH3:9][N+:10]([CH3:19])([CH3:18])[CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>CN(C)C=O.C(O)(=O)C=CC1C=CC=CC=1.C1C=CC=CC=1>[C:3]([O-:4])(=[O:7])[CH:2]=[CH:1][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.[CH3:9][N+:10]([CH3:19])([CH3:18])[CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1
参加物実験手順後処理出典と根拠反応ノート

参加物

7

反応物 3

HCID 887MethanolHCID 66854Benzyltrimethylammonium hydroxideHCID 15676292(Z)-3-chloroprop-1-en-1-ol

生成物 1

HCID 86735285Trimethylbenzyl ammonium cinnamate

試薬・触媒・溶媒 3

HCID 241Benzene溶媒2 回HCID 6228Dimethylformamide溶媒
HCID 8784
2-Propenoic acid, 3-phenyl-
溶媒

実験手順

A 6.5 g amount of polyepichlorohydrin was dissolved in 227 ml of dimethylformamide while heated under a nitrogen atmosphere. In addition, 13.6 g of cinnamic acid was dissolved in 177 ml of benzene and then 38.3 g of a 40% methanol solution of trimethylbenzyl ammonium hydroxide was admixed with the solution. Trimethylbenzyl ammonium cinnamate was isolated when the benzene solvent was evaporated in addition to the methanol and the water formed by the neutralization reaction. The product obtained was admixed with the solution of polyepichlorohydrin and the mixture was reacted at 80° C for 6.5 hours. The reaction mixture was mixed with methanol and 12 g of a rubber-like white polymer was obtained. Infrared spectrum analysis and elemental analysis of the product indicated that the polymer was a photosensitive resin having units 1 and 2 wherein the ratio of 1 to 2 was 71% to 29%. ##STR6##

後処理

  1. temperaturewhile heated under a nitrogen atmosphere

出典と根拠

ORDレコード
ord-9203652fa8d9488c8b113dfd522380ce
出典データセット
uspto-grants-1977_12
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04063953

反応ノート

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