Thioanisole → HCID 178506884、化合物
反応式
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([Li:13])CCC>CCCCCC.O1CCCC1>[C:1]1([S:7][CH2:8][Li:13])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1参加物
5
実験手順
To a solution of 1.17 ml. of thioanisole in 20 ml. of dry tetrahydrofuran were added 8.4 ml. of a 1.2M solution of n-butyllithium in n-hexane at -20° C. and the mixture was stirred at the same temperature of 1.5 hours to give a 0.28M solution of phenylthiomethyllithium in tetrahydrofuran.
出典と根拠
- ORDレコード
- ord-a2b84e137900498fa3034aa88ad675d5
- 出典データセット
- uspto-grants-1977_12
- 特許番号
- US04065632
反応ノート
読み込み中…