2,4-Dichlorophenol → N-methylcarbonyl 2-chloro-3-(2,4-dichlorophenoxy)-6-nitroaniline

HRID 463616

反応式

[CH3:1][C:2]([NH:4][C:5]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][CH:8]=[C:7](Cl)[C:6]=1[Cl:15])=[O:3].[Cl:16][C:17]1[CH:22]=[C:21]([Cl:23])[CH:20]=[CH:19][C:18]=1[OH:24].C(=O)([O-])[O-].[K+].[K+]>CS(C)=O>[CH3:1][C:2]([NH:4][C:5]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][CH:8]=[C:7]([O:24][C:18]2[CH:19]=[CH:20][C:21]([Cl:23])=[CH:22][C:17]=2[Cl:16])[C:6]=1[Cl:15])=[O:3]

参加物

実験手順

A mixture of N-methylcarbonyl 2,3-dichloro-6-nitroaniline (0.90 g, 3.6 mmol), 2,4-dichloro-phenol (0.59 g, 3.6 mmol) and potassium carbonate (1.0 g, 7.2 mmol), in 20 ml of DMSO, is stirred at 90° for 3 hours. The reaction is then cooled and poured onto about 60 g of ice. A yellow solid is collected by filtration to give N-methylcarbonyl 2-chloro-3-(2,4-dichloro-phenoxy)-6-nitroaniline.

後処理

temperatureThe reaction is then cooled
filtrationA yellow solid is collected by filtration

出典と根拠

ORDレコード: ord-58f846855fe64b879956baeae0e90178
出典データセット: uspto-grants-1985_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04544400

反応式

参加物

反応物 3

生成物 1

試薬・触媒・溶媒 1

実験手順

後処理

出典と根拠

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