化工社化工社 化学情報印刷レポート · 研究参考用
1-Butanol → HCID 178454803、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Butanol | HCID 263 | — |
| 反応物 | Water | HCID 962 | — |
| 反応物 | HCID 178476830 | HCID 178476830 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | HCID 178454803 | HCID 178454803 | 81.6% |
反応手順
A solution of α-hydroxyethylphosphinic acid (2.2 g) and 1-butanol (5.0 g) in benzene (30 ml) was heated for 3 hours with removal of water through a Dean-Stark apparatus. After cooling, the reaction mixture was washed with water, dried over magnesium sulfate and concentrated in vacuo to give 2.71 g (81.6%) of n-butyl α-hydroxyethylphosphinate (Compound No. 5).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04544652 |
| 出典データセット | uspto-grants-1985_10 |
| ORD ID | ord-1d8432d027704c71b7d7c4dea8657e9c |
| 出典メモ | uspto-grants-1985_10 |