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llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.8.0
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Acrylic Acid → Isobornylmethacrylate

HRID 464473
ノート
印刷プレビュー

反応式

HRID 464473 の反応式
[C:1](OCC(C)C)(=O)[C:2](C)=[CH2:3].[C:11]([O:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:15])[C:12]([CH3:14])=[CH2:13].C(OCCCC)(=O)C=C.[C:30](O)(=O)[CH:31]=[CH2:32].C1C(C(OOC(C)(C)C)=O)=CC=CC=1>CCCCOCCO.C(O)(C)C>[CH3:13][C:12]([C:11]([O:16][CH:17]1[C@@:31]2([CH3:32])[C:2]([CH3:3])([CH3:1])[C@H:19]([CH2:20][CH2:30]2)[CH2:18]1)=[O:15])=[CH2:14]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

8

反応物 5

HCID 6581Acrylic AcidHCID 7352Isobutyl MethacrylateHCID 7354Butyl MethacrylateHCID 8846Butyl AcrylateHCID 11966tert-Butyl peroxybenzoate2 回

生成物 1

HCID 71311141Isobornylmethacrylate

試薬・触媒・溶媒 2

HCID 3776
Isopropanol
溶媒
HCID 81332-Butoxyethanol溶媒3 回

反応条件

温度
100 °C

実験手順

One hundred twenty-five parts of butyl Cellosolve is heated to 150° C. and a monomer mix consisting of 200 parts of isobutyl methacrylate, 137.5 parts of n-butyl methacrylate, 50 parts of n-butyl acrylate, 62.5 parts of acrylic acid and 50 parts of methacryloxyethyl esters of linseed oil fatty acids and an initiator solution consisting of 1.5 parts of t-butyl perbenzoate dissolved in 10 parts of butyl Cellosolve are added to the 150° C. solvent over three hours at a constant rate. Reaction temperature is held at 150±2° C. throughout the gradual additions and for 15 minutes after the addition of an initiator chaser solution consisting of 3 parts of t-butyl perbenzoate dissolved in 10 parts of butyl Cellosolve. The polymer solution is then cooled to 100° C. and diluted with 174 parts of isopropanol.

後処理

  1. additiona monomer mix
  2. additionare added to the 150° C. solvent over three hours at a constant rate
  3. customReaction temperature
  4. additionafter the addition of an initiator chaser solution

出典と根拠

ORDレコード
ord-41730fe9ee214c4fb80466baa1fae14c
出典データセット
uspto-grants-1985_10
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04547556

反応ノート

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