Hexachlorocyclotriphosphazene → Trichlorotriphenoxycyclotriphosphazene

HRID 465165

反応式

HRID 465165 の反応式
[Cl:1][P:2]1(Cl)[N:7]=[P:6](Cl)([Cl:8])[N:5]=[P:4]([Cl:11])(Cl)[N:3]=1.[O-:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[Na+]>>[Cl:1][P:2]1([O:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[N:7]=[P:6]([Cl:8])([O:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[N:5]=[P:4]([Cl:11])([O:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[N:3]=1

参加物

3

反応物 2

HCID 220225Hexachlorocyclotriphosphazene2 回HCID 4445035Phenolate Sodium

生成物 1

HCID 23418754Trichlorotriphenoxycyclotriphosphazene

実験手順

Examples 8 to 12 below illustrate embodiments of the invention in which hexachlorocyclotriphosphazene (compound 1) is reacted first with sodium phenoxide to produce an intermediate (trischlorotrisphenoxycyclotriphosphazene), 19 which is then reacted without separation with sodium 4-nitrophenoxide to afford tris(4-nitrophenoxy)tris(phenoxy)cyclotriphosphazene 20. The nitro groups of 20 are reduced to afford the corresponding tris amino compound 21 which is then used according to Scheme I or Scheme II shown in FIG. 2 and FIG. 3, respectively.

出典と根拠

ORDレコード
ord-142809559af4447d878cb8abbe1f5e41
出典データセット
uspto-grants-1985_10
特許番号
US04550177

関連ノート

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