Butyltin trichloride → Dibutyltin dichloride

HRID 46615

反応式

HRID 46615 の反応式
[CH2:1]([Sn:5]([CH:18]1[CH2:23][CH2:22][CH2:21][CH2:20][CH2:19]1)([CH:12]1[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13]1)[CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1)[CH2:2][CH2:3][CH3:4].[CH2:24]([Sn:28]([Cl:31])(Cl)[Cl:29])[CH2:25][CH2:26][CH3:27]>C1(C)C(C)=CC=CC=1>[CH:18]1([Sn:5]([Cl:29])([CH:6]2[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]2)[CH:12]2[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17]2)[CH2:23][CH2:22][CH2:21][CH2:20][CH2:19]1.[CH2:1]([Sn:28]([Cl:31])([Cl:29])[CH2:24][CH2:25][CH2:26][CH3:27])[CH2:2][CH2:3][CH3:4]

参加物

5

反応物 2

HCID 14236Butyltin trichlorideHCID 81516Butyltricyclohexylstannane

生成物 2

HCID 12688Dibutyltin dichlorideHCID 76539Stannane, chlorotricyclohexyl-

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

実験手順

A solution of equimolar amounts of butyl tricyclohexyltin and butyltin trichloride in commercial xylene was refluxed for 221/2 hours. Analysis of the reaction mixture obtained showed that the reaction had gone to about 89% completion to form predominantly tricyclohexyltin chloride and dibutyltin dichloride.

後処理

  1. customAnalysis of the reaction mixture obtained

出典と根拠

ORDレコード
ord-c5e415f74b814fec966c82cbe051672a
出典データセット
uspto-grants-1979_11
特許番号
US04174346

関連ノート

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