Tert-Butylhydroquinone → tert-Butyl-1,4-benzoquinone
反応式
[C:1]([C:5]1[CH:11]=[C:10]([OH:12])[CH:9]=[CH:8][C:6]=1[OH:7])([CH3:4])([CH3:3])[CH3:2].S([O-])([O-])(=O)=O.[Na+].[Na+]>[Ag]=O.CCOCC>[C:1]([C:5]1[C:6](=[O:7])[CH:8]=[CH:9][C:10](=[O:12])[CH:11]=1)([CH3:4])([CH3:2])[CH3:3]参加物
5
実験手順
30 g. of tert-butylhydroquinone (Eastman-Kodak) were dissolved in 200 ml. of anhydrous ether and 30 g. of anhydrous sodium sulfate were added. To this mixture was added 60 g. of silver oxide in small increments. An exothermic reaction ensued. After shaking for 20 minutes, the reaction mixture was filtered and the filtrate evaporated under the hood. Yellow crystals of tert-butyl-p-benzoquinone were obtained melting at 55°-60° C.
後処理
- additionTo this mixture was added 60 g
- customAn exothermic reaction
- filtrationthe reaction mixture was filtered
- customthe filtrate evaporated under the hood
出典と根拠
- ORDレコード
- ord-7d9bd9092dee482b80807cca8d558bcc
- 出典データセット
- uspto-grants-1979_11
- 特許番号
- US04174457
反応ノート
読み込み中…