Bisphenol A → 2,2-bis(p-(2-Hydroxy-3-butoxypropyl)phenyl)propane
反応式
[CH2:1]([O:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH:2]1[O:4][CH2:3]1.O[C:11]1[CH:16]=[CH:15][C:14]([C:17]([C:20]2[CH:25]=[CH:24][C:23](O)=[CH:22][CH:21]=2)([CH3:19])[CH3:18])=[CH:13][CH:12]=1>[Cl-].C([N+](C)(C)C)C1C=CC=CC=1>[OH:4][CH:2]([CH2:1][O:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:3][C:11]1[CH:16]=[CH:15][C:14]([C:17]([C:20]2[CH:25]=[CH:24][C:23]([CH2:3][CH:2]([OH:4])[CH2:1][O:5][CH2:6][CH2:7][CH2:8][CH3:9])=[CH:22][CH:21]=2)([CH3:19])[CH3:18])=[CH:13][CH:12]=1参加物
4
実験手順
Butyl glycidyl ether (232.5 g), 2,2-bis(p-hydroxyphenyl)propane (171 g), and benzyltrimethylammonium chloride (4 g) were stirred and heated slowly to 100°. The mixture was kept at 100° for 1 hour, then at 110° for 2 hours, 120° for 1 hour, and 150° for 11/2 hours. The product had an epoxy value of 0.2 equiv./kg.