Hydrochloric Acid → 9,9'-Bianthryl

HRID 47175

反応式

HRID 47175 の反応式
Cl.[CH:2]1[C:15]2[C:14](=O)[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[CH2:7][C:6]=2[CH:5]=[CH:4][CH:3]=1>[Zn].C(O)(=O)C>[CH:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([C:14]=2[C:7]2[C:8]4[C:13]([CH:14]=[C:15]5[C:6]=2[CH:5]=[CH:4][CH:3]=[CH:2]5)=[CH:12][CH:11]=[CH:10][CH:9]=4)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1

参加物

5

反応物 2

HCID 313Hydrochloric AcidHCID 7018Anthrone

生成物 1

HCID 661059,9'-Bianthryl

試薬・触媒・溶媒 2

HCID 23994Zinc触媒HCID 176Acetic Acid溶媒

実験手順

After hydrochloric acid was added to an acetic acid solution of anthrone, it was refluxed upon addition of zinc. Thereafter it was refined in accordance with an ordinary method to obtain 9,9′-bianthryl. After it was added little by little to a melt of aluminum chloride and sodium chloride, the reaction mixture was poured into diluted hydrochloric acid and a solids constituent was collected. The solids constituent thus obtained was refined in accordance with an ordinary method to obtain target dibenzo[a,o]perylene.

出典と根拠

ORDレコード
ord-09a1edf32dea46fb8b70e9767bbae5d4
出典データセット
uspto-grants-2004_03
特許番号
US06699594B1

関連ノート

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