4,4'-Dihydroxybiphenyl → 4-Hydroxybenzoic Acid

HRID 475689

反応式

HRID 475689 の反応式
[OH:1]C1C=CC(C2C=CC(O)=CC=2)=CC=1.C(O)(=O)CCCC[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][C:26]([OH:28])=[O:27]>>[OH:1][C:22]1[CH:21]=[CH:20][C:25]([C:26]([OH:28])=[O:27])=[CH:24][CH:23]=1

参加物

3

反応物 2

HCID 71124,4'-Dihydroxybiphenyl3 回HCID 12736Dodecanedioic Acid2 回

生成物 1

HCID 1354-Hydroxybenzoic Acid

実験手順

Polymerization was carried out in the same way as Example 1, except that (A) preparing materials were changed to 4,4′-dihydroxybiphenyl, dodecanedioic acid, 4-hydroxybenzoic acid, acetic anhydride, and (B) a mixture of 4,4′-dihydroxybiphenyl, dodecanedioic acid, 4-hydroxybenzoic acid, acetic anhydride at a molar ratio of 1.05:1:2:4.1 in which 4,4′-dihydroxybiphenyl was excess by 5 mol % was prepared in a reactor vessel, thereby producing a thermoplastic resin in which 4-hydroxybenzoic acid was copolymerized with the resin of Example 1. A molecular structure, sealed end groups, and a sealing rate of ends are shown in Table 2, and changes in number average molecular mass and thermal conductivity before and after melting are shown in Table 3.

後処理

  1. customPolymerization
  2. customwas prepared in a reactor vessel

出典と根拠

ORDレコード
ord-85734ecb7a8a4e57a35f03491fc78cc1
出典データセット
uspto-grants-2014_01
特許番号
US08637630B2

関連ノート

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