Iodoethane → Acetic acid, (ethylthio)-, ethyl ester
反応式
CC1C=C[C:5]([CH2:6][S:7][CH2:8][C:9]([O:11][CH2:12][CH3:13])=[O:10])=CC=1.ICC.CC[O-].[Na+].SCC(OCC)=O>C(O)C>[CH2:6]([S:7][CH2:8][C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH3:5]参加物
6
実験手順
The procedure is as in Example 29 for the preparation of ethyl (4-methylbenzylthio)acetate, starting with iodoethane (10.5 g), a 2M ethanolic solution of sodium ethylate (37 cc) and ethyl 2-mercaptoacetate (8.1 g) in ethanol (100 cc). Ethyl (ethylthio)acetate (6.9 g) is thereby obtained, and is used in the crude state in the subsequent syntheses.
出典と根拠
- ORDレコード
- ord-cee0fac92b024bf0a2fbecaef95e916c
- 出典データセット
- uspto-grants-1989_12
- 特許番号
- US04886835
反応ノート
読み込み中…