Dimethylamine → Bentazone dimethylammonium

HRID 482304

反応式

HRID 482304 の反応式
[CH3:1][CH:2]([N:4]1[S:14](=[O:16])(=[O:15])[NH:13][C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[C:5]1=[O:6])[CH3:3].[CH3:17][NH:18][CH3:19]>ClCCCl>[CH3:3][CH:2]([N:4]1[S:14](=[O:16])(=[O:15])[NH:13][C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[C:5]1=[O:6])[CH3:1].[CH3:17][NH2+:18][CH3:19]

参加物

4

反応物 2

HCID 674DimethylamineHCID 2328Bentazon

生成物 1

HCID 131720801Bentazone dimethylammonium

試薬・触媒・溶媒 1

HCID 111,2-Dichloroethane溶媒

実験手順

A solution of 24 g of bentazone (IIa) in 216 g of 1,2-dichloroethane was treated with 22.5 g of a 20% strength aqueous solution of dimethylamine with stirring at 30°-50° C. After addition was complete, the aqueous phase was separated off at 50°-60° C. and evaporated to dryness under reduced pressure and at 50°-60° C. 28 g of bentazone-dimethylammonium (m.p. 145°-147° C.; purity >99% according to HPLC analysis for bentazone and titration for dimethylammonium) were obtained.

後処理

  1. additionAfter addition
  2. customthe aqueous phase was separated off at 50°-60° C.
  3. customevaporated to dryness under reduced pressure and at 50°-60° C

出典と根拠

ORDレコード
ord-b46bb2f7c7ef461e94f45d6aa06e7fa5
出典データセット
uspto-grants-1998_08
特許番号
US05795983

関連ノート

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