Dichloromethane → Methyl (2-chloro-2-oxoethoxy)acetate
反応式
[CH3:1][O:2][CH:3](C([O-])=O)[C:4]([O:6][CH3:7])=[O:5].S(Cl)(Cl)=[O:12].[CH2:15]([Cl:17])Cl>>[Cl:17][C:15]([CH2:1][O:2][CH2:3][C:4]([O:6][CH3:7])=[O:5])=[O:12]参加物
4
実験手順
Mono-methyl methoxymalonate (9.8 grams, 0.07 mole), prepared In Example LVI (Compound 214) was reacted with thionyl chloride (15.74 grams, 0.13 mole) in 100 milliliters of methylene chloride in a manner similar to that described in Example LIII Part C, to give 11.06 grams (0.07 mole) of methyl (chlorocarbonyl)methoxyacetate. NMR analysis of the product indicated the following:
出典と根拠
- ORDレコード
- ord-d1e11fa5eb374e43a5e034a94e54dbf9
- 出典データセット
- uspto-grants-1994_03
- 特許番号
- US05292937
反応ノート
読み込み中…