Aluminum sec-butoxide → 2,9-Dihexylpentacene

HRID 488981

反応式

HRID 488981 の反応式
CC(CC)[O-].CC(CC)[O-].CC(CC)[O-].[Al+3].[CH2:17]([C:23]1[CH:24]=[CH:25][C:26]2[CH:27]=[C:28]3[C:41]([C:42](=O)[C:43]=2[CH:44]=1)=[CH:40][C:39]1[C:30]([C:31](=O)[C:32]2[C:37]([CH:38]=1)=[CH:36][CH:35]=[C:34]([CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH3:51])[CH:33]=2)=[CH:29]3)[CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>C1(O)CCCCC1>[CH2:17]([C:23]1[CH:24]=[CH:25][C:26]2[C:43](=[CH:42][C:41]3[C:28]([CH:27]=2)=[CH:29][C:30]2[C:39](=[CH:38][C:37]4[C:32]([CH:31]=2)=[CH:33][C:34]([CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH3:51])=[CH:35][CH:36]=4)[CH:40]=3)[CH:44]=1)[CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]

参加物

4

反応物 2

HCID 61289Aluminum sec-butoxideHCID 22269484HCID 22269484、化合物

生成物 1

HCID 179733722,9-Dihexylpentacene

試薬・触媒・溶媒 1

HCID 7966Cyclohexanol溶媒2 回

反応条件

温度
145 °C

実験手順

A mixture of 5.69 grams of aluminum tri(sec-butoxide) and 49.1 mLs of cyclohexanol was made. To this was added 2.21 grams 3,10-Dihexylpentacene-5,12-dione. The reaction mixture was heated to 145° C. for 24 hours. The mixture was cooled to room temperature and the solid isolated by centrifugation. The solid was stirred with 40 mLs of cyclohexanol and centrifuged two times. The solid was collected by filtration and washed with THF to give 2,9-dihexylpentacene.

後処理

  1. temperatureThe mixture was cooled to room temperature
  2. customthe solid isolated by centrifugation
  3. filtrationThe solid was collected by filtration
  4. washwashed with THF

出典と根拠

ORDレコード
ord-6f4cfd59a8d54b509d5f65523dcba468
出典データセット
uspto-grants-2005_12
特許番号
US06974877B2

関連ノート

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