1-Methylimidazole → 1-Methyl-3-(2',2',2'-trifluoroethyl)imidazolium triflate
反応式
[CH3:1][N:2]1[CH:6]=[CH:5][N:4]=[CH:3]1.[O-:7][S:8]([C:11]([F:14])([F:13])[F:12])(=[O:10])=[O:9].[F:15][C:16]([F:26])([F:25])[CH2:17][I+]C1C=CC=CC=1>C(Cl)Cl>[O-:10][S:8]([C:11]([F:14])([F:13])[F:12])(=[O:9])=[O:7].[CH3:1][N+:2]1[CH:6]=[CH:5][N:4]([CH2:17][C:16]([F:26])([F:25])[F:15])[CH:3]=1参加物
4
実験手順
1-Methylimidazole (0.82 g, 10 mmol) was added to methylene chloride (20 ml), and (2,2,2-trifluoroethyl)(phenyl)iodonium triflate (4.54 g, 10 mmol) was added thereto while stirring in an ice bath. Thereafter, the mixture was stirred at room temperature for 3 hours. Methylene chloride was removed by distillation, and the residue was then dried using a vacuum pump while being heated. Thus, 1-methyl-3-(2′,2′,2′-trifluoroethyl)imidazolium triflate of interest was obtained in a substantially quantitative manner.