4-(4-propoxyphenyl)benzoic Acid → HCID 22925874、化合物

HRID 493045ノート

反応式

HRID 493045 の反応式
[CH2:1]([O:4][C:5]1[CH:10]=[CH:9][C:8]([C:11]2[CH:19]=[CH:18][C:14]([C:15]([OH:17])=[O:16])=[CH:13][CH:12]=2)=[CH:7][CH:6]=1)[CH2:2][CH3:3]>S(Cl)(Cl)=O>[CH2:1]([O:4][C:5]1[CH:6]=[CH:7][C:8]([C:11]2[CH:19]=[CH:18][C:14]([C:15]([O:17][C:8]([CH3:11])([CH3:9])[CH3:7])=[O:16])=[CH:13][CH:12]=2)=[CH:9][CH:10]=1)[CH2:2][CH3:3]

参加物

3

反応物 1

HCID 20636134-(4-propoxyphenyl)benzoic Acid

生成物 1

HCID 22925874HCID 22925874、化合物

試薬・触媒・溶媒 1

HCID 24386Thionyl Chloride溶媒

実験手順

Thionyl chloride (10 ml) was added to 5.0 g (19.5 mmol) of 4-(4-n-propyloxyphenyl)benzoic acid synthesized in the step (ii), and the mixture was refluxed overnight. After an excess amount of thionyl chloride was removed from the resultant mixture, 4′-(n-propyloxy)-4-(tert-butoxycarbonyl)biphenyl was obtained in the same manner as in the Example 104.

後処理

  1. customsynthesized in the step (ii)
  2. temperaturethe mixture was refluxed overnight
  3. customAfter an excess amount of thionyl chloride was removed from the resultant mixture

出典と根拠

ORDレコード
ord-53786bc9e3f642faa0c790f2397e53ac
出典データセット
uspto-grants-2009_05
特許番号
US07534547B2

反応ノート

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