Sodium Hydroxide → 4-Hydroxyphenylsulfonic acid disodium salt

HRID 494362ノート

反応式

HRID 494362 の反応式
O.O.[Na+:3].[OH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([O-:14])(=[O:13])=[O:12])=[CH:7][CH:6]=1.[OH-].[Na+]>C1(C)C=CC=CC=1>[Na+:3].[Na+:3].[OH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([O-:14])(=[O:12])=[O:13])=[CH:7][CH:6]=1.[OH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([O-:14])(=[O:12])=[O:13])=[CH:7][CH:6]=1

参加物

4

反応物 2

HCID 14798Sodium HydroxideHCID 23666329Sodium P-phenolsulfonate dihydrate

生成物 1

HCID 195991314-Hydroxyphenylsulfonic acid disodium salt

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
55 °C

実験手順

A solution of 4-hydroxybenzenesulfonic acid sodium salt dihydrate (20 g, 86 mmol) in 1 N aqueous sodium hydroxide (86 mL, 86 mmol) is stirred and heated at 50-60° C. for 1 h. The solution is concentrated in vacuo at 50° C. to give a solid. The solid is suspended in anhydrous toluene and concentrated in vacuo. This process is repeated twice. The solid is dried at 50° C. at high vacuum for 18 h to give 4-hydroxybenzenesulfonic acid disodium salt.

後処理

  1. concentrationThe solution is concentrated in vacuo at 50° C.
  2. customto give a solid
  3. concentrationconcentrated in vacuo
  4. customThe solid is dried at 50° C. at high vacuum for 18 h

出典と根拠

ORDレコード
ord-a928d54ca39e4db99cf3f1eac1129cbe
出典データセット
uspto-grants-2009_05
特許番号
US07538135B2

反応ノート

読み込み中…