Cyclohexanone → HCID 69497980、化合物

HRID 495321

反応式

HRID 495321 の反応式
[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[OH-:8].[Na+].[CH2:10]([O:16][C:17]1[CH:24]=[CH:23][C:20]([CH:21]=O)=[CH:19][CH:18]=1)[CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]>C(O)C.O>[CH2:10]([O:7][C:1]1[CH:6]=[CH:5][C:4]([CH:21]=[C:20]2[CH2:23][CH2:24][CH2:17][C:18](=[CH:21][C:20]3[CH:23]=[CH:24][C:17]([O:16][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])=[CH:18][CH:19]=3)[C:19]2=[O:8])=[CH:3][CH:2]=1)[CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]

参加物

6

反応物 3

HCID 7967CyclohexanoneHCID 14798Sodium HydroxideHCID 79816p-(Hexyloxy)benzaldehyde

生成物 1

HCID 69497980HCID 69497980、化合物

試薬・触媒・溶媒 2

HCID 702Ethanol溶媒3 回HCID 962Water溶媒

実験手順

Cyclohexanone (2.6 ml, 0.025 mol) was dissolved in ethanol (5 ml), and was added to sodium hydroxide (0.38 g, 0.01 mol) dissolved in water (6 ml) and ethanol (2 ml) and was left to stir for 20 min. 4-Hexyloxybenzaldehyde (10 ml, 0.048 mol), dissolved in ethanol (40 ml), was added and the mixture was stirred at room temperature for 16 h. A yellow crystalline solid was isolated by vacuum filtration and was washed with cold ethanol and dried in a vacuum oven. Yield=4.32 g, 36%. 1H NMR and 13C NMR showed expected signals.

後処理

  1. additionwas added
  2. stirringthe mixture was stirred at room temperature for 16 h
  3. customA yellow crystalline solid was isolated by vacuum filtration
  4. washwas washed with cold ethanol
  5. customdried in a vacuum oven

出典と根拠

ORDレコード
ord-affe587f4e1d4c599e66c79b12e2f716
出典データセット
uspto-grants-2005_09
特許番号
US06939479B2

関連ノート

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