Methyl 2-(1-methylpiperidin-4-ylidene)acetate → Methyl 2-(1-methylpiperidin-4-yl)acetate

HRID 495482ノート

反応式

HRID 495482 の反応式
[CH3:1][O:2][C:3](=[O:12])[CH:4]=[C:5]1[CH2:10][CH2:9][N:8]([CH3:11])[CH2:7][CH2:6]1>[Pd].CCO>[CH3:1][O:2][C:3](=[O:12])[CH2:4][CH:5]1[CH2:6][CH2:7][N:8]([CH3:11])[CH2:9][CH2:10]1

参加物

4

反応物 1

HCID 20672702Methyl 2-(1-methylpiperidin-4-ylidene)acetate

生成物 1

HCID 19425952Methyl 2-(1-methylpiperidin-4-yl)acetate

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

(1-Methyl-piperidin-4-ylidene)-acetic acid methyl ester (Step A) was stirred under H2 overnight (1.1 g of 10% Pd/C and 200 mL EtOH), filtered and evaporated to give (1-methyl-piperidin-4-yl)-acetic acid methyl ester as a yellow oil/white solid.

後処理

  1. filtrationfiltered
  2. customevaporated

出典と根拠

ORDレコード
ord-dacca3ed436b4d0f94be5b29df70d83f
出典データセット
uspto-grants-2005_09
特許番号
US06939874B2

反応ノート

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