Cyclohexene → HCID 69796510、化合物

HRID 495604ノート

反応式

HRID 495604 の反応式
C(OC([N:11]1[CH2:15][CH2:14][CH2:13][C@@H:12]1[CH2:16][O:17][Si:18]([C:21]([CH3:24])([CH3:23])[CH3:22])([CH3:20])[CH3:19])=O)C1C=CC=CC=1.C1CCCCC=1>C(O)C.[Pd]>[Si:18]([O:17][CH2:16][C@H:12]1[CH2:13][CH2:14][CH2:15][NH:11]1)([C:21]([CH3:24])([CH3:23])[CH3:22])([CH3:20])[CH3:19]

参加物

5

反応物 2

HCID 8079CyclohexeneHCID 14629888HCID 14629888、化合物

生成物 1

HCID 69796510HCID 69796510、化合物収率 86.3%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

To a solution of D2 (12.7 g, 0.036 mol) and cyclohexene (excess, 20 ml) in ethanol (100 ml) was added 10% palladium on charcoal catalyst. Reaction was heated at reflux overnight and cooled. Catalyst was filtered and the filtrate concentrated to leave an oil (6.69 g) which was used in the next step without purification.

後処理

  1. customReaction
  2. temperaturewas heated
  3. temperatureat reflux overnight
  4. temperaturecooled
  5. filtrationCatalyst was filtered
  6. concentrationthe filtrate concentrated

出典と根拠

ORDレコード
ord-aa3eccba618748809eeaaf288611ce69
出典データセット
uspto-grants-2005_09
特許番号
US06939891B2

反応ノート

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