Water → 1-[2-[2-[2-(2-Hydroxyethoxy)ethoxy]ethoxy]ethoxy]-9,10-anthraquinone

HRID 496966

反応式

HRID 496966 の反応式
Cl[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][CH:3]=1.O.[CH2:19]([OH:31])[CH2:20][O:21][CH2:22][CH2:23][O:24][CH2:25][CH2:26][O:27][CH2:28][CH2:29][OH:30]>>[OH:30][CH2:29][CH2:28][O:27][CH2:26][CH2:25][O:24][CH2:23][CH2:22][O:21][CH2:20][CH2:19][O:31][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][CH:3]=1

参加物

4

反応物 3

HCID 962WaterHCID 67091-ChloroanthraquinoneHCID 8200Tetraethylene Glycol

生成物 1

HCID 223159141-[2-[2-[2-(2-Hydroxyethoxy)ethoxy]ethoxy]ethoxy]-9,10-anthraquinone

反応条件

温度
120 °C

実験手順

A mixture of 1-chloroanthraquinone (4 gm) potassium carbonate, (4 gm) in tetraethyleneglycol (15 ml) was heated for three hours at 120° C., poured into cool water and filtered off. The solid obtained was chromatographed over silica gel and eluted with methylene chloride:methanol (99:1) gave 1-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]-9,10-anthraquinone. This compound was crystallized from ether to give a yellow crystalline compound.

後処理

  1. additionpoured
  2. filtrationfiltered off
  3. customThe solid obtained
  4. customwas chromatographed over silica gel
  5. washeluted with methylene chloride:methanol (99:1)

出典と根拠

ORDレコード
ord-5eed529334914c5fb74af65902f2fd7b
出典データセット
uspto-grants-2005_09
特許番号
US06949250B2

関連ノート

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