D-(-)-Fructose → Xylulose lyxose

HRID 514642

反応式

HRID 514642 の反応式
[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].[OH:11][CH2:12][C:13]([C@H:15]([C@@H:17]([CH2:19][OH:20])[OH:18])[OH:16])=[O:14].O=C[C@H]([C@H]([C@@H](CO)O)O)O.O=C[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O.OCC([C@H]([C@@H]([C@@H](CO)O)O)O)=O>O>[OH:1][CH2:2][C:3]([C@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])=[O:4].[O:11]=[CH:12][C@H:13]([C@H:15]([C@@H:17]([CH2:19][OH:20])[OH:18])[OH:16])[OH:14]

参加物

7

反応物 5

HCID 5984D-(-)-FructoseHCID 65550LyxoseHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanalHCID 644160aldehydo-D-Xylose2 回HCID 5289590D-Xylulose2 回

生成物 1

HCID 87502838Xylulose lyxose収率 35%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

The catalytic performance of the synthesized Sn-Beta was further tested on the isomerization of xylose, a pentose sugar, in water at 100° C. (FIG. 7c). The products of the reaction are xylulose, lyxose and byproducts from degradation reactions and/or polymerization reactions. The isomerization of xylose to xylulose catalyzed by Sn-Beta is analogous to the isomerization of glucose to fructose. Since the HPLC column used in the analysis cannot separate xylulose and lyxose, the total yields of the two isomers were plotted with the reaction time in FIG. 7c. The isomerization reaction reached equilibrium at 0.5 h with a maximum xylulose+lyxose yield of 35% at xylose conversion of 61%. The xylulose+lyxose yield decreased with time as a result of the side reactions consuming xylose, xylulose and lyxose.

後処理

  1. customat 100° C.
  2. customfrom degradation reactions and/or polymerization reactions
  3. customcannot separate xylulose and lyxose
  4. customthe total yields of the two isomers
  5. customThe isomerization reaction
  6. customat 0.5 h

出典と根拠

ORDレコード
ord-f7fa420009a94a13b8fe22062800686b
出典データセット
uspto-grants-2015_08
特許番号
US09108190B1

関連ノート

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