Sodium Hydroxide → O,O'-Dde

HRID 5223

反応式

HRID 5223 の反応式
[OH-].[Na+].[Cl-].CC(C)CCCCCCCCCCC[NH2+]CC1C=CC=CC=1.[Cl:26][C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=1[CH:33]([C:38]1[CH:43]=[CH:42][CH:41]=[CH:40][C:39]=1[Cl:44])[C:34](Cl)([Cl:36])[Cl:35]>ClC1C=CC=CC=1>[Cl:26][C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=1[C:33]([C:38]1[CH:43]=[CH:42][CH:41]=[CH:40][C:39]=1[Cl:44])=[C:34]([Cl:35])[Cl:36]

参加物

5

反応物 3

HCID 14798Sodium HydroxideHCID 154395O,O'-DdtHCID 86747193Dimethyllaurylbenzylammonium chloride

生成物 1

HCID 14367289O,O'-Dde収率 97.8%

試薬・触媒・溶媒 1

HCID 7964Chlorobenzene溶媒

反応条件

温度
90 °C

実験手順

201.5 g of 28% strength aqueous sodium hydroxide and 2.0 g of dimethyllaurylbenzylammonium chloride were added to a solution of 250 g of 1,1-bis(chlorophenyl)-2,2,2-trichloroethane in 100 g of monochlorobenzene at 50° C. The mixture was heated at reflux (90° C.) for 20 hours. The organic phase was separated by phase separation and was washed three times with 100 g of water. After distillation of the monochlorobenzene, 219.3 g of 1,1-bis(chlorophenyl)-2,2-dichloroethylene were obtained (y=97.8%) with 0.10% of 1,1-bis(chlorophenyl)-2,2,2-trichloroethane.

後処理

  1. temperatureThe mixture was heated
  2. customThe organic phase was separated by phase separation
  3. washwas washed three times with 100 g of water
  4. distillationAfter distillation of the monochlorobenzene

出典と根拠

ORDレコード
ord-89e0dd8d586746a0a5ae5e0d0dd64837
出典データセット
uspto-grants-1993_09
特許番号
US05243110

関連ノート

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