m-Chloroperbenzoic acid → 2-Methyl-propane-2-sulfonic acid (2-bromo-ethyl)-amide
反応式
[Br:1][CH2:2][CH2:3][NH:4][S:5]([C:7]([CH3:10])([CH3:9])[CH3:8])=[O:6].C1C=C(Cl)C=C(C(OO)=[O:19])C=1>>[Br:1][CH2:2][CH2:3][NH:4][S:5]([C:7]([CH3:10])([CH3:9])[CH3:8])(=[O:19])=[O:6]参加物
3
反応条件
- 温度
- 25 °C
実験手順
To a solution of 2-methyl-propane-2-sulfinic acid (2-bromo-ethyl)-amide (0.8 g, 3.5 mmol) was added mCPBA (77%, 0.95 g, 4.2 mmol) and stirred at a temperature of about 25° C. for 2 hrs. The reaction mixture was condensed and purified to provide 2-methyl-propane-2-sulfonic acid (2-bromo-ethyl)-amide as a white solid (0.4 g, 46% yield).
後処理
- customcondensed
- custompurified
出典と根拠
- ORDレコード
- ord-9955dfe097094ee2be6631161f9d01e9
- 出典データセット
- uspto-grants-2016_05
- 特許番号
- US09346808B2
反応ノート
読み込み中…