N-bromobutanimide → 3-Bromo-1,6-diphenylpyrene

HRID 530184ノート

反応式

HRID 530184 の反応式
[C:1]1([C:7]2[C:20]3[C:21]4=[C:22]5[C:17](=[CH:18][CH:19]=3)[CH:16]=[CH:15][C:14]([C:23]3[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=3)=[C:13]5[CH:12]=[CH:11][C:10]4=[CH:9][CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:29]N1C(=O)CCC1=O>CN(C=O)C>[Br:29][C:16]1[CH:15]=[C:14]([C:23]2[CH:24]=[CH:25][CH:26]=[CH:27][CH:28]=2)[C:13]2[C:22]3=[C:21]4[C:10]([CH:9]=[CH:8][C:7]([C:1]5[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=5)=[C:20]4[CH:19]=[CH:18][C:17]=13)=[CH:11][CH:12]=2

参加物

4

反応物 2

HCID 67184N-bromobutanimideHCID 591334031,6-Diphenylpyrene

生成物 1

HCID 866682753-Bromo-1,6-diphenylpyrene

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

Under a flow of argon, 11.8 g of 1,6-diphenylpyrene, 5.93 g of N-bromosuccinimide and DMF were placed into a flask. The resulting mixture was allowed to react at 60° C. for 2 days. After cooling, the reaction solution was filtered, and solids obtained were washed with clean water, methanol and clean water, and solids obtained were dried under a reduced pressure, whereby white solids of 3-bromo-1,6-diphenylpyrene (8.60 g) were obtained.

後処理

  1. customto react at 60° C. for 2 days
  2. temperatureAfter cooling
  3. filtrationthe reaction solution was filtered
  4. customsolids obtained
  5. washwere washed with clean water, methanol and clean water, and solids
  6. customobtained
  7. dry with materialwere dried under a reduced pressure, whereby white solids of 3-bromo-1,6-diphenylpyrene (8.60 g)
  8. customwere obtained

出典と根拠

ORDレコード
ord-1b16e8a6b231404c81fc18bcb948d2f7
出典データセット
uspto-grants-2016_05
特許番号
US09353027B2

反応ノート

読み込み中…