HCID 86644151、化合物 → 2-Ethylpyridin-3-yl acetate
反応式
[C:1]([O:4][C:5]1[C:6]([C:11]#[CH:12])=[N:7][CH:8]=[CH:9][CH:10]=1)(=[O:3])[CH3:2]>C(O)C.O=[Pt]=O>[C:1]([O:4][C:5]1[C:6]([CH2:11][CH3:12])=[N:7][CH:8]=[CH:9][CH:10]=1)(=[O:3])[CH3:2]参加物
4
実験手順
To a solution of 2-ethynylpyridin-3-yl acetate (5.0 g, 31 mmol) in ethanol (50 mL) was added PtO2 (0.50 g, 2.2 mmol). The mixture was degassed with nitrogen and placed under a double-layer balloon of hydrogen. The reaction was stirred at ambient temperature for 30 minutes. The mixture was filtered and concentrated in vacuo to give 2-ethylpyridin-3-yl acetate (5.1 g, 31 mmol) that was used without further purification.
後処理
- customThe mixture was degassed with nitrogen
- filtrationThe mixture was filtered
- concentrationconcentrated in vacuo
出典と根拠
- ORDレコード
- ord-74b56711849d468d9e7f21fdbc87ce66
- 出典データセット
- uspto-grants-2014_10
- 特許番号
- US08853409B2
反応ノート
読み込み中…