4-Phenyl-2-butanol → 4-Methoxybenzyl alcohol

HRID 541177

反応式

HRID 541177 の反応式
O[CH:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6]N=1)[CH3:3].C1(CC[CH:18]([OH:20])C)C=CC=CC=1.C1C2C3[NH+]([O-:30])C(C2)CC1C3>>[CH3:18][O:20][C:4]1[CH:9]=[CH:8][C:7]([CH2:6][OH:30])=[CH:3][CH:2]=1

参加物

4

反応物 3

HCID 613024-Phenyl-2-butanolHCID 86784alpha-Methyl-2-pyridinemethanolHCID 1015366402-Oxido-2-azoniatricyclo[3.3.1.03,7]nonane

生成物 1

HCID 77384-Methoxybenzyl alcohol

実験手順

2-(1-Hydroxyethyl)pyridine (76.8 mg, 0.624 mmol) was oxidized in the same manner as that described in Example 8, (a) (except that Nor-AZADO was used at 3 mol %, and the reaction was performed at room temperature) to obtain the objective compound (66.0 mg; yield, 87.4%). The spectrum data were found to be the same as those obtained in Example 6, (h).

後処理

  1. customwas performed at room temperature
  2. customto obtain
  3. customthe objective compound (66.0 mg; yield, 87.4%)

出典と根拠

ORDレコード
ord-31220d8df9174332927d5f16647c901d
出典データセット
uspto-grants-2014_10
特許番号
US08871981B2

関連ノート

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