2',4'-Dihydroxyacetophenone → Ethyl hexanoate

反応式

C(C1C=CC([CH:14](Br)[CH2:15][CH2:16][CH2:17][CH2:18][C:19]([O:21][CH2:22][CH3:23])=[O:20])=CC=1)C1C=CC=CC=1.CC(C1C=CC(O)=CC=1O)=O>>[C:19]([O:21][CH2:22][CH3:23])(=[O:20])[CH2:18][CH2:17][CH2:16][CH2:15][CH3:14]

参加物

反応物 2

HCID 69902',4'-Dihydroxyacetophenone

HCID 13881964Ethyl 6-(4-benzylphenyl)-6-bromo-hexanoate

生成物 1

HCID 31265Ethyl hexanoate

実験手順

Following the procedure of Example 15, 3.75 g. of ethyl 6-(4-benzylphenyl)-6-bromo-hexanoate and 1.94 g. of 2,4-dihydroxyacetophenone were reacted to provide the intermediate ethyl hexanoate derivative which was then hydrolyzed to provide 0.95 g. of the title product as an oil.

出典と根拠

ORDレコード: ord-75e0d54fe36542b586511d33af2d95ca
出典データセット: uspto-grants-1987_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04661505

反応ノート

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