Acrylamide → Isopropenyl Phosphonic Acid Acrylamide

HRID 543456

反応式

HRID 543456 の反応式
[C:1]([P:4](=[O:7])([OH:6])[OH:5])([CH3:3])=[CH2:2].[C:8]([NH2:12])(=[O:11])[CH:9]=[CH2:10].S(OOS([O-])(=O)=O)([O-])(=O)=O.[NH4+].[NH4+]>O>[C:1]([P:4](=[O:5])([OH:7])[OH:6])([CH3:3])=[CH2:2].[C:8]([NH2:12])(=[O:11])[CH:9]=[CH2:10]

参加物

5

反応物 3

HCID 6579AcrylamideHCID 62648Ammonium PersulfateHCID 557541Isopropenylphosphonic acid

生成物 1

HCID 86739385Isopropenyl Phosphonic Acid Acrylamide

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Aqueous isopropenyl phosphonic acid (47 g; 54%, 0.2 mole) and aqueous acrylamide (28 g, 50%, 0.2 mole) were mixed in a resin kettle as previously described. Ammonium persulfate (6 g) and an additional 84 g of water were then added. The solution was sparged with nitrogen for 1/2 hour and heated to reflux. After 11/2 hours, an additional 6 g of initiator was added followed by an additional 11/2 hours of reflux. The aqueous product was yellow with a final pH of 1.3. The 31PMR showed polymeric absorptions at δ=-30.2 to -33.7 ppm and -25 to -29 ppm.

後処理

  1. customThe solution was sparged with nitrogen for 1/2 hour
  2. temperatureheated to reflux
  3. additionAfter 11/2 hours, an additional 6 g of initiator was added
  4. custom2 hours
  5. temperatureof reflux

出典と根拠

ORDレコード
ord-e397184dad30405c889d840c31b1b210
出典データセット
uspto-grants-1984_05
特許番号
US04446028

関連ノート

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