Acrylic Acid → Zirconium Tetra-acrylate

HRID 550049ノート

反応式

HRID 550049 の反応式
C([O-])CCC.C([O-])CCC.C([O-])CCC.C([O-])CCC.[Zr+4:21].C(OCCOCCO)CCC.COC1C=CC(O)=CC=1.[C:42]([OH:46])(=[O:45])[CH:43]=[CH2:44]>C(O)CCC>[C:42]([O-:46])(=[O:45])[CH:43]=[CH2:44].[C:42]([O-:46])(=[O:45])[CH:43]=[CH2:44].[C:42]([O-:46])(=[O:45])[CH:43]=[CH2:44].[C:42]([O-:46])(=[O:45])[CH:43]=[CH2:44].[Zr+4:21]

参加物

6

反応物 4

HCID 6581Acrylic AcidHCID 8177Diethylene Glycol Monobutyl EtherHCID 90154-MethoxyphenolHCID 160560Zirconium butoxide

生成物 1

HCID 14497031Zirconium Tetra-acrylate

試薬・触媒・溶媒 1

HCID 2631-Butanol溶媒

反応条件

温度
45 °C

実験手順

Into the flask described hereinabove there were placed 509.3 g of zirconium tetrabutanolate, 498.6 g of diethylene glycol monobutyl ether, and 2.8 g of 4-methoxyphenol. To this mixture there were quickly added in drops using a dropping funnel 382.7 grams of acrylic acid. The temperature thereby increased to 45° C. The product remained liquid and stable so that it could be heated to 90° C. during 30 minutes. The co-product butanol was expelled during 1 hour using vacuum up to 200 mbar.

後処理

  1. additionTo this mixture there were quickly added in drops
  2. temperaturestable so that it could be heated to 90° C. during 30 minutes

出典と根拠

ORDレコード
ord-2ed1598de8544613ba84c917ac8e4c2a
出典データセット
uspto-grants-2011_05
特許番号
US07943798B2

反応ノート

読み込み中…