m-Chloroperbenzoic acid → HCID 178508075、化合物
反応式
[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N:3]=1.ClC1C=CC=C(C(OO)=[O:19])C=1>CC(C)=O>[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N+:3]=1[O-:19]参加物
4
実験手順
To a solution of 2-amino-3-nitropyridine (5.0 g; 36 mmol) in acetone (250 mL) was added a solution of m-chloroperbenzoic acid (7.5 g; 100 mmol) in acetone (50 mL). The shiny orange solution was stirred at room temperature for 3 days. The resulting precipitate was dissolved again under heating and the solution poured onto a silica gel column. Column chromatography using acetone as eluant gave the title compound as an orange solid.
後処理
- dissolutionThe resulting precipitate was dissolved again
- temperatureunder heating
- additionthe solution poured onto a silica gel column
出典と根拠
- ORDレコード
- ord-f7313a66e43d401fa561836b9a73d649
- 出典データセット
- uspto-grants-2011_11
- 特許番号
- US08053212B1
反応ノート
読み込み中…