m-Chloroperbenzoic acid → HCID 178508075、化合物

HRID 555221

反応式

HRID 555221 の反応式
[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N:3]=1.ClC1C=CC=C(C(OO)=[O:19])C=1>CC(C)=O>[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N+:3]=1[O-:19]

参加物

4

反応物 2

HCID 70297m-Chloroperbenzoic acidHCID 778873-Nitropyridin-2-ylamine

生成物 1

HCID 178508075HCID 178508075、化合物

試薬・触媒・溶媒 1

HCID 180Acetone溶媒3 回

実験手順

To a solution of 2-amino-3-nitropyridine (5.0 g; 36 mmol) in acetone (250 mL) was added a solution of m-chloroperbenzoic acid (7.5 g; 100 mmol) in acetone (50 mL). The shiny orange solution was stirred at room temperature for 3 days. The resulting precipitate was dissolved again under heating and the solution poured onto a silica gel column. Column chromatography using acetone as eluant gave the title compound as an orange solid.

後処理

  1. dissolutionThe resulting precipitate was dissolved again
  2. temperatureunder heating
  3. additionthe solution poured onto a silica gel column

出典と根拠

ORDレコード
ord-f7313a66e43d401fa561836b9a73d649
出典データセット
uspto-grants-2011_11
特許番号
US08053212B1

関連ノート

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