反応式
[C:1]1(C)C=CC=C(C#N)C=1.NO.[OH:12][N:13]=[C:14]([NH2:21])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>CCO>[OH:12][N:13]=[C:14]([NH2:21])[C:15]1[CH:20]=[CH:19][CH:18]=[C:17]([CH3:1])[CH:16]=1参加物
5
実験手順
The reaction of m-tolunitrile (1 g, 8.54 mmol) and hydroxylamine (0.78 cm3, 12.8 mmol, 1.5 eq) in EtOH (8.5 cm3) was performed in the same manner as in the preparation of N′-hydroxybenzimidamide, to give the product N′-hydroxy-3-methylbenzimidamide (1.25 g, 97.7%) as a white solid, mp 92° C. (lit 88-90° C.).
出典と根拠
- ORDレコード
- ord-4d009a67a7424205a959d14cd7c65ff6
- 出典データセット
- uspto-grants-2011_11
- 特許番号
- US08062429B2
関連ノート
読み込み中…