1-Butanol → Diphenyl Ether
反応式
[CH2:1]([Sn:5](=O)[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[CH2:11]([OH:15])[CH2:12][CH2:13][CH3:14].O.[C:17]1([O:23][C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[C:24]1([O:23][C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1.[O-:15][CH2:11][CH2:12][CH2:13][CH3:14].[O-:15][CH2:11][CH2:12][CH2:13][CH3:14].[CH2:1]([Sn+2:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4]参加物
6
実験手順
Dibutyltin oxide was heated to 190° C. in diphenyl ether and then butanol was dropwise added thereto. Water produced by the reaction and excess butanol were distilled out, whereby a diphenyl ether solution of dibutyltin dibutoxide was prepared.